VIRGINIA CHEMICALS INC -- SODIUM BISULFITE, ANHYDROUS -- 6810-00-097-8145
===================== Product Identification ===================== Product ID:SODIUM BISULFITE, ANHYDROUS MSDS Date:02/01/1988 FSC:6810 NIIN:00-097-8145 === Responsible Party === Company Name:VIRGINIA CHEMICALS INC Address:801 WATER ST City:PORTSMOUTH State:VA ZIP:23704 Country:US Info Phone Num:804-393-3247;804-393-3100 Emergency Phone Num:804-393-3247;800-424-9300(CHEMTREC) CAGE:87698 === Contractor Identification === Company Name:VIRGINIA CHEMICALS INC Address:801 WATER ST Box:City:PORTSMOUTH State:VA ZIP:23704 Country:US Phone:804-893-3247 CAGE:87698 ============= Composition/Information on Ingredients ============= Ingred Name:PYROSULFUROUS ACID, DISODIUM SALT; (SODIUM METABISULFITE) CAS:7681-57-4 RTECS #:UX8225000 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INGESTION: MODERATELY TOXIC. SKIN: MAY CAUSE SEVERE SKIN INJURY. INHALATION: NO SPECIFIC INFORMATION. EYE: MAY CAUSE SEVERE EYE INJURY. CONTACT WITH STRONG ACIDS WILL GENERATE SULFUR DIOXIDE IN QUANTITIES WHICH, WITHOUT ADEQUATE VENTILATION, MAY BE HAZARDOUS. CHRONIC: NO SPECIFIC INFORMATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SENSITIVE PERSONS MAY EXPERIENCE RESPIRATORY ALLERGIC REACTIONS. ======================= First Aid Measures ======================= First Aid:REMOVE FROM EXPOSURE. INGESTION: SEEK MEDICAL ATTENTION. SKIN: WASH EXPOSED AREA THOROUGHLY WITH WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: IF BREATHING IS DIFFICULT, ADMINISTER OXYGE N. IF BREATHING HAS STOPPED, ADMINISTERARTIFICIAL RESUSCITATION. EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:USE ALCOHOL-TYPE FOAM, CARBON DIOXIDE, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN ALL SPILLED MATERIAL. DO NOT FLUSH TO SURFACE WATER. COLLECT DRY MATERIAL IN SUITABLE CONTAINERS. RQ IS 5000 POUNDS (2270 KG). UNCONTROLLED SPILLS EXCEEDING 5000 LBS SHOULD BE REPORTED TO NATI ONAL RESPONSE CENTER (800-424-8802). Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY AREA AWAY FROM ACIDS AND OXIDIZING AGENTS. Other Precautions:PERSONS SUFFERING FROM ASTHMA OR OTHER RESPIRATORY PROBLEMS SHOULD AVOID ANY CONTACT OR EXPOSURE TO SODIUM BISULFITE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST MASK OR ACID GAS RESPIRATOR FITTED WITH DUST FILTERS. Ventilation:EXHAUST FANS TO PROVIDE LOCALIZED VENTILATION. Protective Gloves:CHEMICAL WORKERS RUBBER GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:SAFETY SHOWERS AND EYE WASH FOUNTAINS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Decomp Temp:Decomp Text:>302F,>150C Spec Gravity:1.31 Solubility in Water:40% @ 15C Appearance and Odor:FREE FLOWING WHITE CRYSTAL. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS AND ACIDS. Stability Condition to Avoid:SODIUM BISULFITE, ANHYDROUS DECOMPOSES AT 302F (150C) WITH LIBERATION OF SULFUR DIOXIDE. Hazardous Decomposition Products:SULFUR DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF COLLECTED MATERIAL CAN BE DISSOLVED IT MAY BE DISCHARGED TO AN INDUSTRIAL WASTE WATER COLLECTION SYSTEM. CONSULT LOCAL, STATE OR FEDERAL REGULATORY AGENCIES BEFORE DISPOSING OF ANY MATERIAL. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.