THE CHLORAMONE CORP -- SODIUM HYPOCHLORITE -- 6810-00N057650
===================== Product Identification ===================== Product ID:SODIUM HYPOCHLORITE MSDS Date:04/17/1986 FSC:6810 NIIN:00N057650 === Responsible Party === Company Name:THE CHLORAMONE CORP Address:RIVER RD & RED LION CREEK Box:294 City:DELAWARE CITY State:DE ZIP:19706 Country:US Info Phone Num:215-439-8531 Emergency Phone Num:302-834-4558 CAGE:1BH83 === Contractor Identification === Company Name:THE CHLORAMONE CORP Address:RIVER RD & RED LION CREEK Box:City:DELAWARE CITY State:DE ZIP:19706 Country:US Phone:215-439-8531 CAGE:1BH83 ============= Composition/Information on Ingredients ============= Ingred Name:HYPOCHLOROUS ACID, SODIUM SALT; (SODIUM HYPOCHLORITE) (CERCLA) HOUSEHOLD BLEACH CNTNS <7% AVAIL CHLORINE (ING 2) CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ING 1:(6.67 %WT) W/ABOUT 0.3-0.5 EXCESS NAOH FOR STABILITY CONTROL. INDUST BLEACH CNTNS 7-15% AVAIL CHLORINE (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:(6.67-13.06% WT) W/ABOUT 0.05-0.85 EXCESS NAOH. RTECS #:9999999ZZ Ingred Name:CNDTNS (STAB):DECREASE IN PH, & CONTAM W/HEAVY METALS, SUCH AS NICKEL, COBALT, COPPER AND IRON. RTECS #:9999999ZZ Ingred Name:HAZ DECOMP PRODS:DECOMP PRODS, WHICH DEPEND UPON PH, TEMP & TIME, ARE SODIUM CHLORIDE, SODIUM CHLORATE AND OXYGEN. RTECS #:9999999ZZ Ingred Name:OTHER PREC:SPILLAGE OCCURS. IF SHIPPED, MUST COMPLY W/DOT, ETC. SHIPPING REGS. IF CLSD CNTNRS BECOME HEATED, (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:CNTNRS SHOULD BE VENTED TO RELS DECOMP PRODS (MAINLY OXYG UNDER NORM DECOMP). DO NOT MIX/CONTAM W/AMMONIA, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:HYDROCARBONS, ACIDS, ALCOHOLS, ETHERS. RTECS #:9999999ZZ Ingred Name:PROT GLOVES:EXPOSED TO SOLUTIONS STRONGER THAN HOUSEHOLD BLEACH (7%). RTECS #:9999999ZZ Ingred Name:EYE PROT:AND FULL LENGTH FACE SHIELD . RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:EYEWASH FOUNTAINS SHOULD BE AVAILABLE IN STORAGE AND HANDLING AREAS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50(ORAL,RAT):5.25%:13G/KG,12.5%:5G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRTATING EFFECTS INCREASE WITH STRENGTH OF SOLUTION AND TIME OF EXPOSURE. NHAL:FUMES FROM SPILLS ARE VERY IRRITATING TO MUCOUS MEMBRANES. VERY LITTLE HAZARD FROM PROPERLY STORED SOLUTION. SKIN: IRRITANT, REDDENING OF SKIN, SKIN DAMAGE. EYE:SEVERE IRRIT.(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:INGESTION:CAUSES IRRITATION OF MEMBRANES OF THE MOUTH, THROAT, AND STOMACH PAIN AND POSSIBLE ULCERATION. CHRONIC:CONSTANT IRRITANT TO EYES, THROAT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:COPIOUS EYE WASH W/WATER FOR AT LST 15 MIN HOLDING EYELIDS APART TO ENSURE FLUSHING OF ENTIRE EYE SURF. CONSULT AN EYE SPECIALIST IMMED. SKIN:WASH CONTAM AREAS W/PLENTY OF WATER. REMOVE CONTAM CL THG & FOOTWEAR & WASH CLTHG BEFORE REUSE. SEEK MED ATTN IMMED. INHAL:GET PERSON OUT OF CONTAM AREAS TO FRESH AIR. INGEST:DRINK WATER, MILK, & OBTAIN MED ATTN. DO NOT USE BAKING SODA/ACID ANTIDOTES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NONFLAMMABLE Upper Limits:NONFLAMMABLE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . AVOID FUMES FROM SPILLED/EXPOSED LIQ, DILUTE COPIOUSLY, VENT & BE PREPARED TO USE RESP PROT IF (SUP DAT) Unusual Fire/Explosion Hazard:BLEACH DECOMPOSES WHEN HEATED; DECOMP PRODS MAY CAUSE CNTNRS TO RUPTURE/EXPLODE. VIGOROUS REACTION POSS W/ORG MATL OR OXIDIZING AGENTS; MAY RESULT IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH W/WATER TO DILUTE AS MUCH AS POSS, AVOID HEAT & CONTAM W/ACID MATLS. DO NOT USE COMBUST MATLS SUCH AS SAWDUST TO ABSORB HYPOCHLORITE. IF NOT DILUTED, MAY SERIOUSLY AFFECT AQUATIC LIFE. DO NOT AL LOW SPILLED MATL TO ENTER SEWERS OR STREAMS. Neutralizing Agent:REDUCING AGENTS SUCH AS BISULFITES/FERROUS SALT SOLNS; SOME HEAT WILL BE PRDCED. ====================== Handling and Storage ====================== Handling and Storage Precautions:NORMAL HANDLING OF HOUSEHOLD BOTTLED BLEACH REQUIRES SAFETY REQUIREMENTS AS STATED ON THE LABELS. Other Precautions:FULL PROT SHOULD BE PROVIDED WHEN HNDLG BULK SHIPMENTS OF CONC, INDUST BLEACH SOLNS. STORE IN VENTED, CLSD, CLEAN, NON-CORR CNTNRS IN COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT & NOT ADJACENT TO CH EMS WHICH MAY REACT W/BLEACH IF (ING 6) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN FUMES ARE PRESENT USE NIOSH/MSHA APPROVED RESPIRATOR WITH ACID TYPE CANISTER. Ventilation:NO SPECIAL VENTILATION REQUIRED UNLESS BLEACH IS EXPOSED TO DECOMPOSITION CONDITION; I.E., SPILLS OR ACIDIC CONDITIONS. Protective Gloves:USE RUB/PLATIC GLOVES WHEN (ING 9) Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 10) Other Protective Equipment:USE RUB APRON, ETC. TO PROT BODY FROM ANY SPLASHING CNDTNS. USE RUB PROT SHOES IF SPILLS OCCUR. SFTY SHOWER & (ING 11) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV:50 GPL-1.08, 100 GPL-1.14, 140 GPL-1.21 (H*2O=1). VP:VP OF WATER PLUS DECOMP PROD VP. MP:(50 GPL,22F,-5.6C)(100 GPL10F,-12C)(140 GPL-4F,-20C). % VOLAT:VARIABLE-WATER VAP PLUS PRODS OF DECOMP . FIRE FIGHT PROC:NEEDED. ACID CONTAM WILL PRDCE VERY IRRIT FUMES SIMILAR TO CHLORINE GAS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:230F,110C Melt/Freeze Pt:M.P/F.P Text:SUPP DATA Vapor Pres:SUPP DATA Spec Gravity:SUPP DATA pH:12 Solubility in Water:COMPLETE Appearance and Odor:(LIGHT YELLOW-GREEN) ODOR-(PUNGENT LIKE CHLORINE) Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO AVOID CONTAMINATION WITH HEAVY METALS (ACTS AS CATALYSTS), REDUCING AGENTS, ORGANICS, ETHER, AMMONIA, ACIDS. Stability Condition to Avoid:SOLN OF SODIUM HYPOCHLORITE ARE FAIRLY STABLE IN CONC BELOW 1%. STABILITY DECREASES W/CONC, HEAT, LIGHT EXPOS, (ING 4) Hazardous Decomposition Products:HYPOCHLOROUS ACID (HOCL), CHLORINE, HYDROCHLORIC ACID. COMPOSITION DEPENDS UPON TEMP & DECREASE IN PH. ADDNL (ING 5) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . REDUCE WITH CHEMS LISTED IN NEUTS. KEEP ON ALKALINE SIDE AND DILUTE WITH COPIOUS QUANTITIES OF WATER. MAIN END PRODUCT IS SALT WATER. (N*ACI) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.