UNION CARBIDE CORPORATION -- ACETYLENE -- 6830-00-286-5434
===================== Product Identification ===================== Product ID:ACETYLENE MSDS Date:04/01/1987 FSC:6830 NIIN:00-286-5434 === Responsible Party === Company Name:UNION CARBIDE CORPORATION Address:39 OLD RIDGEBURY ROAD Box:NA City:DANBURY State:CT ZIP:06817-0001 Country:US Info Phone Num:ROUTINE INFO CONTACT LOCAL SUPPLIER Emergency Phone Num:1-800-822-4357 CANADA 514-640-6400 CAGE:36346 === Contractor Identification === Company Name:HAMPTON ROADS SUPPLY UNION CARBIDE LINDE DIVISION Address:3450 VIRGINIA BEACH BLVD Box:12567 City:NORFOLK State:VA ZIP:23502-3123 Country:US CAGE:7D711 Company Name:UNION CARBIDE CORP LINDE DIV Address:39 OLD RIDGEBURY RD Box:City:DANBURY State:CT ZIP:06817-0001 Country:US Phone:800-822-4357; 304-744-3487 CAGE:36346 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLENE CAS:74-86-2 Fraction by Wt: 100% ACGIH TLV:750 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:INGST;UNLIKELY RT BUT FRSTBITE OF LIPS/MOUTH MAY RESULT FROM CONTACT W/LIQ. IF LIQ IS INGST MAY CAUSE NAUSEA.SKIN:NO HRMFL EFFCTS EXPECTED FROM VAPOR.LIQ MAY CAUSE FRSTBITE.EYE:VAPOR/LIQ MAY CAUSE I RRITATION/FRSTBITE.INHL:ASPHYXIANT. MODTCONCNT OF VAPOR HDACHE,DROWINS,DIZZINS,NAUSEA,VOMITING,EXCS SALIVAT,& UNCONSCNS. Effects of Overexposure:NONE CURRENTLY KNOWN. Medical Cond Aggravated by Exposure:A NKOWLEDGE OF AVAILABLE TOXICOLOGY INFORMATION & PHYSICAL/CHEMICAL PROPERTIES OF MATERIAL SUGGEST THAT OVEREXPOSURE IS UNLIKELY TO AGGRAVATE EXISTNGMEDICAL CONDITIONS. ======================= First Aid Measures ======================= First Aid:INGST: IF LIQUID IS SWALLOWED DONOT INDUCE VOMITING. CALL A PHYSICIAN. SKIN: FOREXPOSURE TO LIQUID, FLUSH W/WATER & WARM FROSTBITE AREA (NOT TO EXCEED 105F). INCASE OF MASSIVE EXPSR REMOVE CLTHNG W/SH OWERING W/WARM WTR. EYE: IMMEDIATELYFLUSH W/WTR FOR 15 MINUTES. SEEK AN OPTHALMOLOGIST URGENTLY.INHL:REMOVE TO FRSH AIR. IF BREATHING STOPS,GIVE ARTIFCL RESP. OR OXYGEN IF BREATHING IS DIFFICULT. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:OF/-17.8C Autoignition Temp:Autoignition Temp Text:****** Lower Limits:100 Upper Limits:2.3 Extinguishing Media:STOP FLW OF GAS W/O RISK WHILE CONT WTR SPRAY.ALLOW FIRE TO BRN OUT.ON SITE FIRE BRIGADES MUST COMPLY W/OSHA29CFR1910 Fire Fighting Procedures:EVACUATE ALL PERSONNEL FROM DANGER AREA. REMOVE ALL CONTNRS FROM AREA OF FIRE. ON SITE FIRE BRIGADES MUST COMPLY WITH OSHA 29 CFR1910.156. Unusual Fire/Explosion Hazard:EXTRMLY FLAMBLE GAS. FORMS EXPLSV MIXT W/AIR & OXIDIZING AGENTS. CONTAINER MAY RUPTURE DUE TO HEAT OR FIRE. DO NOT EXTNGSH FLAMES DUE TO POSS. EXPLSV REIGNITN ================== Accidental Release Measures ================== Spill Release Procedures:FORMS EXPLSV MIXTR W/AIR.IMMEDLY EVACUATE PERSNL FROM AREA.USE SCBA W/NEEDED.REMOVE ALL SOURCE OF IGNITION.REDUCE VAPORS W/FOG OR FINE WTR SPRAY. SHUT OFF LEAK IF W/O RISK.VENTL AREA OF LEAK OR MOVE LEAKING CONTAINER TO WELL VENTL AREA. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTL AREA. DONOT STORE NEAR OPEN FLAMES.DONOT GRND CYLNDR.DONOT STORE W/ OXYGEN/OXIDIZERS.PROTECT CYLND FROM PHYSCL DAMAGE Other Precautions:DO NOT STRIKE ARC ON CYLINDER. HEAT/SPARKS DURING USE COULD BE SOURCE OF INGNTN.CLOSE VALVE WHEN NOT IN USE & WHEN EMPTY. NEVER WORK ON PRESSURIZED SYSTEMS. STORE CYLINDERS IN UPRIGHT POSITION SECU RED TO PREVENT FALLING OVER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN CONFINED SPACE OR WHERE LOCAL EXHAUST/VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. SELECT AS PER OSHA 29 CFR 1910.134 Ventilation:LOCAL EXHAUST OR BOTH, TO KEEP FUMES/GASES BELOW TLV'S IN WORKER'S BREATHING ZONE/THE GENERAL AREA. Protective Gloves:WELDING GLOVES RECOMMENDED Eye Protection:GOGGLES W/FILTER LENS/PROTECTION GOGGLES Other Protective Equipment:AS NEEDED, WEAR HAND,HEAD & BODY PROTECTION WHICH HELPS TO PREVENT INJURY FROM RADIATION & SPARKS. SEE ANSI Z49.1 Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NA Vapor Pres:635 PSIG Vapor Density:0.91 Spec Gravity:NA Evaporation Rate & Reference:NA Solubility in Water:SLIGHT Appearance and Odor:COLORLESS GAS AT NORMAL TEMPERATURE AND PRESSURE; GARLIC LIKE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO COPPER, SILVER, MERCURY, OR THEIR ALLOYS, OXIDIZING AGENTS, ACIDS, HALOGENS, MOISTURE. Stability Condition to Avoid:STABLE AS SHIPPED. AVOID USE AT PRESSURE ABOVE 15 PSIG Hazardous Decomposition Products:THERMAL DECOMP OR BURNING MAY PRODC CO/CO2H2.OTHER DECOMPSTNPROD OF NRML OPERT ORIGINATE FROM VOLATILIZATION,OXIDATION. Conditions to Avoid Polymerization:ELEVATED TEMPERATURE AND PRESSURE AND/OR THE PRESENCE OF A CATALYST. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD ANY PRODUCT,RESIDUE,DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IN COMPLIANCE W/FEDERAL,STATE,& LOCAL REGULATIONS.PREVENT WASTE FROM CONTAMINATING SURROUNDING AREA. KEEP PERSONNEL AWAY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.