BERRYMAN PRODUCTS -- B12 CHEMTOOL 0101 -- 6850-00N050535 ===================== Product Identification =====================
Product ID:B12 CHEMTOOL 0101
MSDS Date:11/01/1985
FSC:6850
NIIN:00N050535
=== Responsible Party ===
Company Name:BERRYMAN PRODUCTS
Address:3800 E RANDALL MILL
City:ARLINGTON
State:TX
ZIP:76011
Country:US
Info Phone Num:817-640-2376
Emergency Phone Num:817-640-2376
CAGE:0TAY6
=== Contractor Identification ===
Company Name:BERRYMAN PRODUCTS
Address:3800 E RANDALL MILL
Box:City:ARLINGTON
State:TX
ZIP:76011
Country:US
Phone:817-640-2376
CAGE:0TAY6
============= Composition/Information on Ingredients =============
Ingred Name:SPILL PROC:SALVAGE TANK. REMAINDER MAY BE TAKEN UP ON
ABSORB MATL & SHOVELED INTO CONTAINERS.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 9:NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. HAVE
PATIENT LIE DOWN & KEEP WARM. COVER EYES TO EXCLUDE LIGHT.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: >9%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: >9%
OSHA PEL:1000PPM
ACGIH TLV:750PPM/1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHANOL (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: >4%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: >9%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM
Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: >9%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: >5%
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500 STEL
Ingred Name:VM & P NAPHTHA
CAS:64742-89-8
Fraction by Wt: >5%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
Ingred Name:SUPDAT:NO. 90-118). .
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FIRST AID PROC:THROAT. AFTER VOMIT HAS BEEN INDUCED, GIVE 2
TEASPOONSFUL OF BAKING SODA IN GLASS OF WATER. (ING 10)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:NOTE: TOLUENE APPEARS ON NAVY LISTING
OF OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HNDLG &
EXPOS INFO . ACUTE:INHAL:AN ESTHETIC. IRRITATES RESP TRACT. MAY
CAUSE SERIOUS NERV SYS DEPRESS, DMG TO KIDNEYS, BLOOD, (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:NERVES, LIVER & LUNGS. RPTED EXPOS
OVER TLV MAY CAUSE BLINDNESS. SKIN:PRIMARY IRRIT, DEFAT, DERM.
EYE:PRIMARY IRRIT, REDNESS, TEARING, BLURRED VISION. CHRONIC:VAP
HARMFUL. BRTHG OF VAP MAY CA USE IRRIT. LIQ CAUSES EYE IRRIT. LIQ
MAY CAUSE SKIN IRRIT. ABSORPTION THRU SKIN MAY BE HARMFUL. MAY BE
FATAL OR (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:WASH THORO W/SOAP & WATER. EYES:IMMED FLUSH W/PLENTY OF
WATER FOR AT LEAST 15 MINS & CALL PHYS. REMOVE & WASH CONTAMD CLTHG
BEFORE REUSE. (DISCARD CONTAMD SHOES). INHAL:AFTER HIGH VAP EXPOS,
REMO VE TO FRESH AIR. IF BRTHG IS DFCLT GIVEOXYG. IF BRTHG HAS
STOPPED GIVE ARTIF RESP. CALL PHYS. INGEST:INDUCE VOMIT PROMPTLY
ACCORDING TO PHYS INSTRUCTIONS/BY HAVE PATIENT STICK FINGER DOWN
(ING 9)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:1F,-17C
Lower Limits:2.9
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO*1 OR FOAM) FOR CLASS
I B.
Fire Fighting Procedures:NIOSH/MSHA APPRVD AIR SUPPLIED BRTHG MASKS.
WATER SPRAY MAY BE INEFTIVE ON FIRE BUT CAN PROTECT FIRE FIGHTERS &
COOL CLSD CNTNRS. USE FOG NOZZ IF H*20 IS USED.
Unusual Fire/Explosion Hazard:EXTREMELY FLAM!! KEEP CNTNR TIGHTLY CLSD.
ISOLATE FROM OXIDIZERS, HEAT, SPARKS, NON-EXPLO PROOF ELECTRIC
EQUIP & OPEN FLAME. APPLYING TO HOT SURF REQS (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SM:MOP UP W/ABSORB MATL & TRANSFER TO HOOD.
LG:ISOLATE FROM OXIDIZERS, HEAT, SPARKS, ELECTRIC EQUIP & OPEN
FLAME. UNPROTECTED PERSONS SHOULD BE KEPT FROM AREA UNTIL CLEANED
UP. STOP SPILL AT SOURCE. D IKE AREA TO PVNT SPREAD. PUMP LIQ TO
(ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:VAPS MAY IGNITE EXPLOSIVELY. PVNT VAP
BUILD-UP. PUT OUT PILOT LIGHTS & TURN OFF IGNIT SOURCES DURING USE
& UNTIL ALL VAPS ARE GONE. EMPTY CNTNR HAZ!
Other Precautions:VAPS MAY SPREAD LONG DIST. DO NOT STOR ABOVE
49C/120F. STORE LG AMTS IN STRUCTURES MADE FOR OSHA CLASS I B LIQS.
AVOID FREE FALL OF LIQ. GROUND CNTNRS WHEN POURING. DO NOT FLAME
CUT, SAW, BRAZE OR WEL D. CONTINE ALL LABEL PRECAUTIONS!
============= Exposure Controls/Personal Protection =============
Respiratory Protection:VENT TO KEEP AIR BELOW 65 PPM. IF OVER TLV, USE
NIOSH/MSHA APPRVD SELF-CONTAINED AIR PACK. CONSULT SFTY EQUIP
SUPPLIER. USE EXPLOSION PROOF ELECTRIC EQUIPMENT.
Ventilation:LOCAL:PREFERABLE. MECHANICAL(GENERAL):ACCEPTABLE.
Protective Gloves:"IMERVIOUS" GLOVES .
Eye Protection:ANSI APPVD CHEMICAL GOGGLES .
Other Protective Equipment:OSHA STANDARD FOOTWEAR.
Work Hygienic Practices:WASH HANDS THORO AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ:SPECIAL PRECAUT. EFTS OF OVEREXP:CAUSE BLINDNESS IF
SWALLOWED. CANNOT BE MADE NON POISONOUS. ANIMAL STUDIES CLEARLY
DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS,
BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL
ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH) PUBLICATION(ING 8)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>133F,>56C
Vapor Pres:60.4 @20C
Vapor Density:2.5
Spec Gravity:0.822 (WATER=1)
Evaporation Rate & Reference:14.8 (ETHER=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR, WATER-WHITE, KETOEN ODOR
Percent Volatiles by Volume:144.7
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATE.
Stability Condition to Avoid:ISOLATE FROM HEAT, SPARKS, NON-EXPLOSION
PROOF ELECTRIC EQUIPMENT & OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE FROM
BURNING.
==================== Disposal Considerations ====================
Waste Disposal Methods:SM:EVAP UNTIL ALL VAPS ARE GONE. DISPOSE OF
REMAINDER BY LEGALLY APPLIC METHODS. LG:RECYCLE/INCINERATE
OSBSERVING LOCAL, STATE & FEDERAL HEALTH, SAFETY & POLLUTION LAWS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.