MALLINCKRODT INC, SCIENCE PRODUCTS DIV -- HYDROGEN PEROXIDE SOLUTION, 30% -- 6810-00-299-8506
===================== Product Identification ===================== Product ID:HYDROGEN PEROXIDE SOLUTION, 30% MSDS Date:04/06/1989 FSC:6810 NIIN:00-299-8506 === Responsible Party === Company Name:MALLINCKRODT INC, SCIENCE PRODUCTS DIV Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:606-987-7000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN PEROXIDE SOLUTION (8% TO 40% PEROXIDE) CAS:7722-84-1 RTECS #:MX0899000 Fraction by Wt: 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:1 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS NOT ESTABLISHED. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:VAPORS AND LIQUID ARE CORROSIVE AND IRRITATING. INHALATION OF MIST MAY BURN THE MUCOUS MEMBRANE OF THE NOSE & THROAT. INGESTION MAY CAUSE BLISTERING OR TISSUE DESTRUCTION. SKIN CONTACT MAY CAUSE IRRIT ATION AND DISCOLORATION. VAPORS ARE VERY CORROSIVE AND IRRITATING TO THE EYES AND LIQUID MAY CAUSE TISSUE DESTRUCTION. Explanation of Carcinogenicity:IRAC "3": NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS. Effects of Overexposure:VAPORS AND LIQUID ARE CORROSIVE AND IRRITATING. INGESTION OF LARGE AMOUNTS MAY CAUSE ABDOMINAL PAIN, VOMITING AND DIARRHEA AS WELL AS BLISTERING OR TISSUE DESTRUCTION. SKIN CONTACT MAY CAUSE DISCOLORA TION AND PAIN. EYE CONTACT MAY CAUSE PAIN, REDNESS AND BLURRED VISION. SPLASHES MAY CAUSE TISSUE DESTRUCTION. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER WHILE REMOVING CONTAMINATED CLOTHING. INHALATION: REMOVE TO FR ESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER OR MILK TO DRINK. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Autoignition Temp:Autoignition Temp Text:NONE Extinguishing Media:WATER SPRAY FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PRESS DEMAND OR OTHER POSITIVE PRESSURE MODE Unusual Fire/Explosion Hazard:CONTACT WITH OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT COMBUSTION. DRYING OF CONCENTRATED HYDROGEN PEROXIDE ON COMBUSTIBLE MATERIALS MAY CAUSE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE WITH LARGE AMOUNT OF WATER & HOLD IN A POND OR DIKED AREA UNTIL THE H2O2 DECOMPOSES FOLLOWED BY DISCHARGE INTO A SUITABLE TREATMENT SYSTEM. DO NOT FLUSH UNDILUTED MATERIAL TO SEWER. RINSE EMPTY CONTAINERS WITH WATER BEFORE DISCARDING. Neutralizing Agent:NEUTRALIZE WITH SODIUM METABISULFITE OR SODIUM SULFITE AFTER DILUTING WITH WATER ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED DARK AREA SEPARATED FROM COMBUSTIBLE SUBSTANCES, REDUCING AGENTS, STRONG BASES & ORGANICS. SUGGEST ROTATION OF STOCK. Other Precautions:CAUTION! CAUSTIC MATERIAL. CAUSES FIRES WITH ORGANIC MATERIALS. VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL REQUIRE PROTECTIVE CLOTHING. CONTAIN & RECOVER LIQUID WHEN POSSIBLE. DO NOT RETURN S PILLED MATERIAL TO ORIGINAL CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED A FULL FACEPIECE CHEMICAL CARTRIDGE RESPIRATOR MAY BE WARN, IN GENERAL, UP TO 100 TIMES THE TLV OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY THE RESPIRATOR SUPPLIER, WHICHEVER IS LESS. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS. Protective Gloves:WEAR IMPERVIOUS GLOVES Eye Protection:CHEMICAL SAFETY GOGGLES WITH FACE SHEILD Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS TO PREVENT SKIN CONTACT. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL. Supplemental Safety and Health MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. FOR HIGH VAPOR OR MIST CONCENTRATIONS, WEAR A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD. CONTAINERS MUST BE VENTED, B UT CHECK PERIODICALLY FOR BULGING CONTAINERS WHICH CAN BURST FROM PRESSURE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:226F,108C Melt/Freeze Pt:M.P/F.P Text:-13F,-25C Vapor Pres:25 Vapor Density:1.17 Spec Gravity:1.11 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID. ACRID ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO A STRONG OXIDIZER, REACTS VIOLENTLY UPON CONTACT WITH MANY ORGANIC SUBSTANCES, PARTICULARLY TEXTILE AND PAPER. Stability Condition to Avoid:UNSTABLE WITH HEAT, MAY RESULT IN DANGEROUS PRESSURES. SOLUTION CAN DECOMPOSE VIOLENTLY UPON HEATING. Hazardous Decomposition Products:DECOMPOSES TO WATER AND OXYGEN WITH RAPID HEAT RELEASE. USE VENTED CONTAINERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZE AFTER DILUTING TO 5-10% PEROXIDE. DO NOT FLUSH UNDILUTED MATERIAL TO SEWER. AFTER DECOMPOSITION, DISCHARGE INTO A SUITABLE TREATMENT SYSTEM IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGUL ATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.