MALLINCKRODT INC, SCIENCE PRODUCTS DIV -- HYDROGEN PEROXIDE SOLUTION, 30% -- 6810-00-299-8506
=====================  Product Identification  =====================

Product ID:HYDROGEN PEROXIDE SOLUTION, 30%
MSDS Date:04/06/1989
FSC:6810
NIIN:00-299-8506
=== Responsible Party ===
Company Name:MALLINCKRODT INC, SCIENCE PRODUCTS DIV
Address:PARIS BYPASS
Box:M
City:PARIS
State:KY
ZIP:40361
Country:US
Info Phone Num:606-987-7000
Emergency Phone Num:314-982-5000
CAGE:62910
=== Contractor Identification ===
Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910

=============  Composition/Information on Ingredients  =============

Ingred Name:HYDROGEN PEROXIDE SOLUTION (8% TO 40% PEROXIDE)
CAS:7722-84-1
RTECS #:MX0899000
Fraction by Wt: 30%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 PPM
ACGIH TLV:1 PPM

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50 (RAT) IS NOT ESTABLISHED.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:VAPORS AND LIQUID ARE CORROSIVE AND
    IRRITATING. INHALATION OF MIST MAY BURN THE MUCOUS MEMBRANE OF THE
    NOSE & THROAT. INGESTION MAY CAUSE BLISTERING OR TISSUE
    DESTRUCTION. SKIN CONTACT MAY CAUSE IRRIT ATION AND DISCOLORATION.
    VAPORS ARE VERY CORROSIVE AND IRRITATING TO THE EYES AND LIQUID MAY
    CAUSE TISSUE DESTRUCTION.
Explanation of Carcinogenicity:IRAC "3": NOT CLASSIFIABLE AS TO ITS
    CARCINOGENICITY TO HUMANS.
Effects of Overexposure:VAPORS AND LIQUID ARE CORROSIVE AND IRRITATING.
    INGESTION OF LARGE AMOUNTS MAY CAUSE ABDOMINAL PAIN, VOMITING AND
    DIARRHEA AS WELL AS BLISTERING OR TISSUE DESTRUCTION. SKIN CONTACT
    MAY CAUSE DISCOLORA TION AND PAIN. EYE CONTACT MAY CAUSE PAIN,
    REDNESS AND BLURRED VISION. SPLASHES MAY CAUSE TISSUE DESTRUCTION.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
    DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
    MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
    MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH WITH PLENTY
    OF WATER WHILE REMOVING CONTAMINATED CLOTHING. INHALATION: REMOVE
    TO FR ESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
    BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: DO NOT INDUCE
    VOMITING. IF CONSCIOUS, GIVE WATER OR MILK TO DRINK. GET MEDICAL
    ATTENTION.

=====================  Fire Fighting Measures  =====================

Flash Point:NOT COMBUSTIBLE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:WATER SPRAY FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH
    APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
    OPERATED IN PRESS DEMAND OR OTHER POSITIVE PRESSURE MODE
Unusual Fire/Explosion Hazard:CONTACT WITH OXIDIZABLE SUBSTANCES MAY
    CAUSE EXTREMELY VIOLENT COMBUSTION. DRYING OF CONCENTRATED HYDROGEN
    PEROXIDE ON COMBUSTIBLE MATERIALS MAY CAUSE FIRE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:DILUTE WITH LARGE AMOUNT OF WATER & HOLD IN A
    POND OR DIKED AREA UNTIL THE H2O2 DECOMPOSES FOLLOWED BY DISCHARGE
    INTO A SUITABLE TREATMENT SYSTEM. DO NOT FLUSH UNDILUTED MATERIAL
    TO SEWER. RINSE EMPTY  CONTAINERS WITH WATER BEFORE DISCARDING.
Neutralizing Agent:NEUTRALIZE WITH SODIUM METABISULFITE OR SODIUM
    SULFITE AFTER DILUTING WITH WATER

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED DARK
    AREA SEPARATED FROM COMBUSTIBLE SUBSTANCES, REDUCING AGENTS, STRONG
    BASES & ORGANICS. SUGGEST ROTATION OF STOCK.
Other Precautions:CAUTION! CAUSTIC MATERIAL. CAUSES FIRES WITH ORGANIC
    MATERIALS. VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL
    REQUIRE PROTECTIVE CLOTHING. CONTAIN & RECOVER LIQUID WHEN
    POSSIBLE. DO NOT RETURN S PILLED MATERIAL TO ORIGINAL CONTAINER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF THE TLV IS EXCEEDED A FULL FACEPIECE CHEMICAL
    CARTRIDGE RESPIRATOR MAY BE WARN, IN GENERAL, UP TO 100 TIMES THE
    TLV OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY THE RESPIRATOR
    SUPPLIER, WHICHEVER  IS LESS.
Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
    KEEP EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS.
Protective Gloves:WEAR IMPERVIOUS GLOVES
Eye Protection:CHEMICAL SAFETY GOGGLES WITH FACE SHEILD
Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING,
    INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS TO PREVENT SKIN
    CONTACT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
    WITH THIS MATERIAL.
Supplemental Safety and Health
MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA.
    FOR HIGH VAPOR OR MIST CONCENTRATIONS, WEAR A SUPPLIED AIR FULL
    FACEPIECE RESPIRATOR OR AIRLINED HOOD. CONTAINERS MUST BE VENTED, B
    UT CHECK PERIODICALLY FOR BULGING CONTAINERS WHICH CAN BURST FROM
    PRESSURE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE.

==================  Physical/Chemical Properties  ==================

HCC:D1
Boiling Pt:B.P. Text:226F,108C
Melt/Freeze Pt:M.P/F.P Text:-13F,-25C
Vapor Pres:25
Vapor Density:1.17
Spec Gravity:1.11
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID. ACRID ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:NO
A STRONG OXIDIZER, REACTS VIOLENTLY UPON CONTACT WITH MANY ORGANIC
    SUBSTANCES, PARTICULARLY TEXTILE AND PAPER.
Stability Condition to Avoid:UNSTABLE WITH HEAT, MAY RESULT IN
    DANGEROUS PRESSURES. SOLUTION CAN DECOMPOSE VIOLENTLY UPON HEATING.
Hazardous Decomposition Products:DECOMPOSES TO WATER AND OXYGEN WITH
    RAPID HEAT RELEASE. USE VENTED CONTAINERS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:NEUTRALIZE AFTER DILUTING TO 5-10% PEROXIDE. DO
    NOT FLUSH UNDILUTED MATERIAL TO SEWER. AFTER DECOMPOSITION,
    DISCHARGE INTO A SUITABLE TREATMENT SYSTEM IN ACCORDANCE WITH
    LOCAL, STATE AND FEDERAL REGUL ATIONS.

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 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.